Section 18.3 Diffusion with Heterogeneous Chemical Reaction Deriving eq. 18.3-9 for the flux of A through a film of thickness delta when the reaction 2A->B takes place at z=delta. It is assumed that all of the A is converted instantly at the catalytic surface. > restart; > deq:=NAz=-c*DAB*D(xA)(z)+xA(z)*(NAz+NBz); Eq. 18.0-1 > NBz:=-(1/2)*NAz; From the stoichiometry of the reaction > s:=dsolve({deq,xA(0)=xA0},xA(z)); Using the BC eq. 18.3-6 at z=0. > assign(s); > xA:=unapply(xA(z),z); > eq:=xA(delta)=0; The BC eq. 18.3-7 at z=delta. > solve(eq,NAz);
> This is identical to 18.3-9 except for the division by -2 of the top and bottom of the ln function. Now we will try Example 18.3-1: see ex1831.mws and ex1831b.mws