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The syllabus below indicates course content and not the specific order in which the material will be covered. The syllabus is subject to change.
1. Introduction to Thermodynamics
-Equilibrium
-Work
-Exact and inexact differentials, basic multivariable calculus
-Energy: internal energy, kinetic energy, potential energy
-Heat
2. The First Law of Thermodynamics
-closed and open systems
-conservative and non-conservative forces, state functions
3. The Second Law of Thermodynamics
-statistical thermodynamics: irreversibility and the attainment of equilibrium
-definition of temperature and entropy
-heat reservoirs
-heat capacity and specific heat
4. The Third Law of Thermodynamics
5. The Ideal Gas
-equation of state
-isothermal, reversible expansions
-adiabatic reversible expansions6. Maxwell Relations
-Definition of Helmholtz Free Energy, Gibbs Free Energy, Enthalpy
-throttling processes
-First Law for Open Systems
7. Non-Ideal Fluids
-virial expansions
-compressibility factors
-van der Waals equation of state
8. Phase Transitions
-intensive variables, molar quantities
-Gibbs Phase Rule
-the critical point
-Clausius-Clapeyron equation
-thermodynamic diagrams
9. Heat Changes
-heat changes of reaction and formation
-combustion reactions
10. Heat Engines
-Carnot cycles
-refrigerators
-power generation
11.Introduction to Solution and Multicomponent Thermodynamics.
-Chemical Potential and Phase Equilibria
-Fugacity
-Ideal Solutions
Last updated: Jan 10, 2002
© J. L. Goveas 2002
jlgoveas@rice.edu