9.5 Heat Conduction with Chemical Heat Source
First we will derive eq. 9.5-24
> restart; > Sc:=T->Sc1*(T-To)/(T1-To); eq. 9.5-1 > A:=Pi*R^2; The bed area is constant > Qcond:=z->A*qz(z); The rate of heat conduction at position z > Qconv:=z->A*rho1*v1*Cp*(T(z)-T0); The rate of thermal heat convection at position z > LHS:=limit((Qcond(z+dz)-Qcond(z)+Qconv(z+dz)-Qconv(z))/(A*dz),dz=0); Deriving the Left Hand Side of eq. 9.5-8 > de:=simplify(LHS=Sc(T(z))); eq. 9.5-8 with eq. 9.5-1 for Sc > qz:=z->-keff*D(T)(z); Fourier's Law assuming an effective thermal conductivity > de; This looks like eq 9.5-11 > with(PDEtools,dchange); Used in DEs to change variables. New in Vr5. > transf:={z=Z*L,T=To+Theta*(T1-To)}; A set that gives the transformation to get old variables from the new ones. Note the use of {} to make a set. > Newde:=dchange(transf,de,[Theta(Z),Z]); Arguments in dchange: 1) the set of transformations 2) the differential equation 3) the new functional relation > v1:=B*keff/(rho1*Cp*L); eq. 9.5-21 to replace v1 with B > Sc1:=N*rho1*v1*Cp*(T1-To)/L; eq. 9.5-22 to replace Sc1 with N > Newde; > eq24:=simplify(Newde*L^2/(B*keff*(T1-To))); Canceling out the common terms in the expression, we get eq. 9.5-24
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