Example 18.2-2 Determination of Diffusivity
>  restart;
>  z2:=z1+17.1*cm;
>  Ptot:=755*mmHg;
>  T:=273.15*K;
From the ceng301 data and the function vappr, we get for the vapor
pressure of CCl4:
vappr(273.15)
ans =
5.5562 <-- 41.67mmHg?? The text gives 33 mmHg.
> vapP:=5.5562*kPa; > mmHg:=kPa*101.325/760;xA1:=vapP/Ptot; > pB1:=(1-xA1)*Ptot;pB2:=Ptot; > S:=0.82*cm^2;evaprA:=.00208*cm^3/hr; > SGCCl4:=1.595; From Felder & Rousseau, Table B.2 > rhoA:=SGCCl4*g/cm^3; > MWA:=153.82*g/mol; From Appendix E.1 of BSL > hr:=3600*second;NA:=evaprA*rhoA/MWA/S; > c:=Ptot/Rgas/T; > Rgas:=82.0578*cm^3*atm/mol/K; > atm:=101.325*kPa;c; > DAB:=NA*(z2-z1)/c/log(1/(1-xA1)); From eq. 18.2-14 using xA2=0.
[Maple Math]
> 
The book found a higher value due to the lower vapor pressure of CCl4 at 0C.